During the ArcticNet annual cruises of the research icebreaker CCGS Amundsen, characteristics of the near-surface atmosphere are monitored in conjunction with surface sea water properties to observe the relationship between the surface micro-climate and the air-sea exchange, with particular interest in CO2. Central to this integrated dataset is an eddy covariance system used to monitor fluxes of CO2, H2O, heat and momentum. The system continuously sampled the following variables at a rate of 10 Hz (instrument used to collect each variable is in parentheses, and approximate instrument height above surface is indicated): 3D wind velocity (Gill WindMaster Pro and Campbell Scientific CSAT3 ultra-sonic anemometers) - 15m; sonic air temperature (3D ultra-sonic anemometers) - 15m; CO2 molar concentration (two LI7500A open path gas analyzers) - 15m; H2O molar concentration (two LI7500A open path gas analyzers) - 15m; CO2 mixing ratio (LI7000 closed path system) - 15m; H2O mixing ratio (LI7000 closed path system) - 15m; and 3D ship motion - angular rates and accelerations (MotionPak, Systron Donner) - 13m. All instruments were mounted on a meteorological tower on the bow of the research icebreaker CCGS Amundsen.

Samples collected by rosette or hand-deployed niskin, directly transferred into acid-washed and backed glass vials with teflon-lined silicone septa caps, and frozen at -20 or -80 C. Analyses conducted by high-temperature catalytic combustion and calibrated again standards provided by the University of Miami. In 2002, all samples were total organic carbon (TOC), and in 2003-04, all samples were dissolved organc carbon (DOC, filtered through combusted GFF), and TOC was also collected at full stations at in surface waters at the overwintering site.

During the ArcticNet annual cruises of the research icebreaker CCGS Amundsen, characteristics of the surface sea water (temperature, salinity, dissolved CO2 and O2) are monitored in conjunction with properties of the near-surface atmosphere (basic meteorological elements, incident radiation, CO2 concentration) to observe the relationship between the surface microclimate and the air-sea exchange, with particular interest in CO2. Central to this project, the following variables were measured continuously at 1 minute intervals using a custom-built pCO2 equilibrator attached to the ship's clean water intake: -pCO2sw (LI7000 gas analyzer) -Equilibrator water temperature

During the ArcticNet annual cruises of the research icebreaker CCGS Amundsen, characteristics of the surface sea water (temperature, salinity, dissolved CO2 and O2) are monitored in conjunction with properties of the near-surface atmosphere (basic meteorological elements, incident radiation, CO2 concentration) to observe the relationship between the surface microclimate and the air-sea exchange, with particular interest in CO2. Central to this integrated dataset is an under-way sea water pCO2 system (General Oceanics 8050) attached to the ship's clean water intake. The following variables were measured continuously and logged at 1 minute intervals: -pCO2sw (LI7000 gas analyzer) -Equilibrator water temperature -conductivity -pH -dissolved O2

As part of this project, an eddy covariance system was deployed to monitor fluxes of CO2, H2O, heat and momentum. The following variables were continuously sampled at a rate of 10 Hz (instrument used to collect each variable is in parentheses, and approximate instrument height above surface is indicated): -3D wind velocity (Gill R3 and Gill Windmaster Pro ultra-sonic anemometers) - 15m -Sonic air temperature (Gill R3 and Gill Windmaster Pro ultra-sonic anemometers) - 15m -CO2 molar concentration (LI7500 open path gas analyzer) - 15m -H2O molar concentration (LI7500 open path gas analyzer) - 15m -CO2 mixing ratio (LI7000 integrated into a closed path system) - 15m -H2O mixing ratio (LI7000 integrated into a closed path system) - 15m -3D ship motion - angular rates and accelerations (MotionPak, Systron Donner) All instruments were mounted on a meteorological tower on the bow of the research icebreaker CCGS Amundsen.

During the ArcticNet annual cruises of the research icebreaker CCGS Amundsen, characteristics of the surface sea water (temperature, salinity, dissolved CO2 and O2) are monitored in conjunction with properties of the near-surface atmosphere (basic meteorological elements, incident radiation, CO2 concentration) to observe the relationship between the surface microclimate and the air-sea exchange, with particular interest in CO2. Central to this integrated dataset is an under-way sea water pCO2 system (General Oceanics 8050) attached to the ship's clean water intake. The following variables were measured continuously and logged at 1 minute intervals: -pCO2sw (LI7000 gas analyzer) -Equilibrator water temperature -conductivity -pH -dissolved O2

During the ArcticNet annual cruises of the research icebreaker CCGS Amundsen, characteristics of the near-surface atmosphere are monitored in conjunction with surface sea water properties to observe the relationship between the surface micro-climate and the air-sea exchange , with particular interest in CO2. Central to this integrated dataset is an eddy covariance system used to monitor fluxes of CO2, H2O, heat and momentum. The system continuously sampled the following variables at a rate of 10 Hz (instrument used to collect each variable is in parentheses, and approximate instrument height above surface is indicated): -3D wind velocity (Gill WindMaster Pro ultra-sonic anemometer) - 15m -Sonic air temperature (Gill WindMaster Pro ultra-sonic anemometer) - 15m -CO2 molar concentration (LI7500 open path gas analyzer) - 15m -H2O molar concentration (LI7500 open path gas analyzer) - 15m -CO2 mixing ratio (LI7000 integrated into a closed path system) - 15m -H2O mixing ratio (LI7000 integrated into a closed path system) - 15m -3D ship motion - angular rates and accelerations (MotionPak, Systron Donner) - 13m All instruments were mounted on a meteorological tower on the bow of the research icebreaker CCGS Amundsen.

During the ArcticNet annual cruises of the research icebreaker CCGS Amundsen, characteristics of the near-surface atmosphere are monitored in conjunction with surface sea water properties to observe the relationship between the surface micro-climate and the air-sea exchange , with particular interest in CO2. Central to this integrated dataset is an eddy covariance system used to monitor fluxes of CO2, H2O, heat and momentum. The system continuously sampled the following variables at a rate of 10 Hz (instrument used to collect each variable is in parentheses, and approximate instrument height above surface is indicated): -3D wind velocity (Gill WindMaster Pro ultra-sonic anemometer) - 15m -Sonic air temperature (Gill WindMaster Pro ultra-sonic anemometer) - 15m -CO2 molar concentration (LI7500 open path gas analyzer) - 15m -H2O molar concentration (LI7500 open path gas analyzer) - 15m -CO2 mixing ratio (LI7000 integrated into a closed path system) - 15m -H2O mixing ratio (LI7000 integrated into a closed path system) - 15m -3D ship motion - angular rates and accelerations (MotionPak, Systron Donner) - 13m All instruments were mounted on a meteorological tower on the bow of the research icebreaker CCGS Amundsen.

During the ArcticNet annual cruises of the research icebreaker CCGS Amundsen, characteristics of the near-surface atmosphere are monitored in conjunction with surface sea water properties to observe the relationship between the surface micro-climate and the air-sea exchange , with particular interest in CO2. Central to this integrated dataset is an eddy covariance system used to monitor fluxes of CO2, H2O, heat and momentum. The system continuously sampled the following variables at a rate of 10 Hz (instrument used to collect each variable is in parentheses, and approximate instrument height above surface is indicated): -3D wind velocity (Gill R3 and Gill Windmaster Pro ultra-sonic anemometer) - 15m -Sonic air temperature (Gill R3 and Gill Windmaster Pro ultra-sonic anemometer) - 15m -CO2 molar concentration (LI7500 open path gas analyzer) - 15m -H2O molar concentration (LI7500 open path gas analyzer) - 15m -CO2 mixing ratio (LI7000 integrated into a closed path system) - 15m -H2O mixing ratio (LI7000 integrated into a closed path system) - 15m -3D ship motion - angular rates and accelerations (MotionPak, Systron Donner) - 13m All instruments were mounted on a meteorological tower on the bow of the research icebreaker CCGS Amundsen.

During the ArcticNet annual cruises of the research icebreaker CCGS Amundsen, characteristics of the near-surface atmosphere are monitored in conjunction with surface sea water properties to observe the relationship between the surface micro-climate and the air-sea exchange , with particular interest in CO2. Central to this integrated dataset is an eddy covariance system used to monitor fluxes of CO2, H2O, heat and momentum. The system continuously sampled the following variables at a rate of 10 Hz (instrument used to collect each variable is in parentheses, and approximate instrument height above surface is indicated): -3D wind velocity (Gill R3 and Gill Windmaster Pro ultra-sonic anemometer) - 15m -Sonic air temperature (Gill R3 and Gill Windmaster Pro ultra-sonic anemometer) - 15m -CO2 molar concentration (LI7500 open path gas analyzer) - 15m -H2O molar concentration (LI7500 open path gas analyzer) - 15m -CO2 mixing ratio (LI7000 integrated into a closed path system) - 15m -H2O mixing ratio (LI7000 integrated into a closed path system) - 15m -3D ship motion - angular rates and accelerations (MotionPak, Systron Donner) - 13m All instruments were mounted on a meteorological tower on the bow of the research icebreaker CCGS Amundsen.